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Amongst the usual bits of rose quartz, malachite and galena on the
French market stall, one specimen caught my eye. Made of small cafe au
lait cubes, it looked familiar, but the name was strange - ANKERITE.
However it wasn't from Turkey, as the box was stamped MAROC. The stall
owner wasn't any wiser about its composition. But it had aroused my
curiosity, and as it wasn't expensive, I bought it.
Back home, to
my surprise, none of the popular books on minerals listed it, nor did
some more detailed mineralogy textbooks, and I was beginning to think it
a French name for something else when my eyes lit up on finding it in
the Encyclopaedia Britannica. But the crystals were described as
rhombic. Surely mine were cubes? Looking again at my specimen, but more
closely, I saw my error - they were rhombs. So what is the connection
with Ankara?
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Pale buff,
brown-weathering, rhombohedral ankerite crystals, occurred as an
extensive crust on joint surface in sandstone. Nant Helen
Opencast. Specimen National Museum of Wales (NMW 99.37G.M.19),
photo by D.I. Green, © National Museum of Wales. |
Well, there
isn't any, just as Ilmenite doesn't come from Ilminster. Anker was the
man after whom the mineral is named. It is a derivative of dolomite, in
which some of the magnesium has been replaced by iron. Which is why it
looked familiar - Dave Green had shown us a face of dolomite crystals in
the Forest of Dean. So it is part of a series of carbonate minerals,
ranging from Calcite, which is pure calcium carbonate, and fizzes with
vinegar, through Dolomite, a calcium-magnesium carbonate, which needs to
be heated with strong hydrochloric acid before it fizzes significantly,
then Ankerite, a calcium, magnesium and iron carbonate, which reacts
with cold hydrochloric acid. As the iron concentration increases,
Siderite, or pure iron carbonate is the last member of this branch of
the series. (The other branch terminates in pure magnesium carbonate as
the mineral Magnesite, used in fire bricks and face powder.) .More
rigorously, Ankerite is defined as dolomite in which more than 20% of
the magnesium atoms have been replaced by iron. After heavy firing it
becomes magnetic, calcite and dolomite do not. It varies from white, and
cream, to brown or red and has a white streak. It has a hardness of 4 on
Mohs' scale, a Specific Gravity of about 3, and occurs in sedimentary
rocks as a result of "low temperature metasomatism" - whatever that
means - as well as commonly containing some manganese. And " it is found
in deposits of iron ore with chalybite". What is that? Searching for
chalybite yielded "see siderite" which turns out to be just another name
for it. But hasn't chalybite something to do with mineral waters?
Paraphrasing Bloxham, "chalybeate" waters contain "iron carbonate
dissolved in carbonic acid, and hence the rusty deposits when they are
exposed to air". He also mentions other sorts of mineral waters
described as "hepatic" or "sulphureous" . - "Harrogate water is
eminently sulphureous and its nauseous odour is due to sulphuretted
hydrogen". He hadn't tried the water from the Pump Room in Bath, or at
Tunbridge Wells, both of which are also eminently sulphureous.
Chalybite, or
siderite is an important constituent of "Spathic" iron ore. And spathic
comes from the German "spath" or spar - which refers to any translucent
non-metallic mineral, such as felspar and fluorspar, that can be easily
split into layers, or else a fragment of such a mineral. Iron rich
dolomites are also loosely known as Brown-Spar, Pearl-Spar or
Bitter-Spar. Siderite comes from sideros, the Greek for iron, but it is
also the name of a type of iron meteorite.
Professor
Mathias Anker (1771 - 1843) was a mineralogist from Arnold
Schwarzenegger's province of Styria in south - east Austria , but he
didn't discover it. It was Wilhelm von Haidinger, a colleague of Mohs,
who recognised it as a distinct mineral species , in 1825, and named it
in his honour.
Sources
include :-
1) Bloxham's
Chemistry 9th Edition, Churchill, London 1904
2)1911encyclopedia.org
3) en.wikipedia.org
4) Chamber's 21st Century Dictionary
5) McGraw-Hill Encyclopedia of Science and Technology
6) Encyclopaedia Britannica 1947 edition
7) answers.com
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